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Robert Floyd Curl Jr. (August 23, 1933 – July 3, 2022) was an American chemist who was Pitzer–Schlumberger Professor of Natural Sciences and professor of chemistry at . He was awarded the Nobel Prize in Chemistry in 1996 for the discovery of the buckminsterfullerene, and hence the class of materials, along with (also of Rice University) and of the University of Sussex.


Early life and education
Born in Alice, Texas, United States, Curl was the son of a minister.
(2025). 9780816054992, Facts on File. .
Due to his father's missionary work, his family moved several times within southern and southwestern Texas, and the elder Curl was involved in starting the San Antonio Medical Center's Methodist Hospital.
(2025). 9780787617523, The Gale Group.
Curl attributes his interest in chemistry to a he received as a nine-year-old, recalling that he ruined the finish on his mother's porcelain stove when boiled over onto it. He is a graduate of Thomas Jefferson High School in San Antonio, Texas. His high school offered only one year of chemistry instruction, but in his senior year his chemistry teacher gave him special projects to work on.

Curl received a Bachelor of Arts in chemistry from (now Rice University) in 1954. He was attracted to the reputation of both the school's academics and football team, and the fact that at the time it charged no tuition. He earned his in chemistry from the University of California, Berkeley, in 1957. Robert F. Curl, Jr At Berkeley, he worked in the laboratory of , then dean of the college of chemistry, with whom he would become a lifelong collaborator. Curl's graduate research involved performing infrared spectroscopy to determine the of .


Scientific career
Curl was a postdoctoral fellow at Harvard University with E. B. Wilson, where he used microwave spectroscopy to study the bond rotation barriers of molecules. After that, he joined the faculty of Rice University in 1958. He inherited the equipment and graduate students of George Bird, a professor who was leaving for a job at Polaroid. Curl's early research involved the microwave spectroscopy of . His research program included both experiment and theory, mainly focused on detection and analysis of using microwave spectroscopy and tunable lasers. He used these observations to develop the theory of their and hyperfine structure, as well as information about their structure and the kinetics of their reactions.


Nobel Prize
Curl's research at Rice involved the fields of infrared and microwave spectroscopy. Curl's research inspired Richard Smalley to come to Rice in 1976 with the intention of collaborating with Curl. In 1985, Curl was contacted by Harold Kroto, who wanted to use a laser beam apparatus built by Smalley to simulate and study the formation of in stars. Smalley and Curl had previously used this apparatus to study such as and . They were initially reluctant to interrupt their experiments on these semiconductor materials to use their apparatus for Kroto's experiments on carbon, but eventually gave in.

They indeed found the long carbon chains they were looking for, but also found an unexpected product that had 60 carbon atoms. Over the course of 11 days, the team studied and determined its structure and named it buckminsterfullerene after noting its similarity to the for which the architect Buckminster Fuller was known. This discovery was based solely on the single prominent peak on the mass spectrograph, implying a chemically inert substance that was geometrically closed with no . Curl was responsible for determining the optimal conditions of the carbon vapor in the apparatus, and examining the spectrograph. Curl noted that James R. Heath and Sean C. O'Brien deserve equal recognition in the work to Smalley and Kroto. The existence of this type of molecule had earlier been theorized by others, but Curl and his colleagues were at the time unaware of this. Later experiments confirmed their proposed structure, and the team moved on to synthesize endohedral fullerenes that had a metal atom inside the hollow carbon shell. The , a class of molecules of which buckminsterfullerene was the first member discovered, are now considered to have potential applications in and molecular scale electronics. Robert Curl's 1985 paper entitled "C60: Buckminsterfullerine", published with colleagues H. Kroto, J. R. Heath, S. C. O’Brien, and R. E. Smalley, was honored by a Citation for Chemical Breakthrough Award from the Division of History of Chemistry of the American Chemical Society, presented to Rice University in 2015. The discovery of fullerenes was recognized in 2010 by the designation of a National Historic Chemical Landmark by the American Chemical Society at the Richard E. Smalley Institute for Nanoscale Science and Technology at Rice University in Houston, Texas.

After winning the Nobel Prize in 1996, Curl took a quieter path than Smalley, who became an outspoken advocate of nanotechnology, and Kroto, who used his fame to further his interest in science education, saying, "After winning a Nobel, you can either become a scientific pontificator, or you can have some idea for a new science project and you can use your newfound notoriety to get the resources to do it. Or you can say, 'Well, I enjoy what I was doing, and I want to keep doing that.'" True to that humility, when asked by the President of Rice what he would like, following the Nobel announcement, he asked that a bike rack be installed closer to his office and laboratory. Robert F. Curl (1933–2022), Nature, 17 Aug 2022


Later research
Curl's later research interests involved physical chemistry, developing genotyping and sequencing instrumentation, and creating photoacoustic sensors for using quantum cascade lasers. He is known in the residential college life at Rice University for being the first master of .

Curl retired in 2008 at the age of 74, becoming a University Professor Emeritus, Pitzer-Schlumberger Professor of Natural Sciences Emeritus, and Professor of Chemistry Emeritus at Rice University.


Personal life
Curl married Jonel Whipple in 1955, with whom he had two children. He cycled to his office and lab and every week played bridge with the Rice Bridge Brigade. Curl died in on July 3, 2022, at the age of 88.


Awards and honors
  • Clayton Prize, Institute of Mechanical Engineers, 1957
    (2025). 9781860941511, Imperial College Press. .
  • Alexander von Humboldt Senior US Scientist Award, University of Bonn, Germany, 1984
  • Fellow of the National Academy of Sciences, 1997
  • Golden Plate Award of the American Academy of Achievement, 1997
  • Fellow of the American Academy of Arts and Sciences, 1998
  • International Prize for New Materials, American Physical Society, 1992
  • Nobel Prize in Chemistry, Royal Swedish Academy of Sciences, 1996
  • Johannes Marcus Marci Award in Spectroscopy, 1998
  • Centenary Medal, Royal Society of Chemistry, 1999
  • Honorary Fellow, The Royal Society of New Zealand, 2001
  • University of Bochum Research Prize, 2004
  • National Historic Chemical Landmark, American Chemical Society, 2010
  • Citation for Chemical Breakthrough Award, Division of History of Chemistry, American Chemical Society, 2015
  • Fellow of the Optical Society of America


Selected publications
Journal articles: Technical reports:


External links

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